B05N – Support Engineering for the Stabilization of Highly Dispersed Metal Catalysts
This project aims at the modification of various oxidic supports through the incorporation of f-, d- and p-block elements. Through this systematic support engineering approach, highly dispersed metal catalysts will be synthesized with the aim to investigate the balance act between stabilization and poisoning in great detail. The catalytic activity of single atoms, cluster and particles on chemically modified supports will be explored in the gas phase for CH4, NH3 and VOC oxidation reactions with the ultimate goal to establish structure-reactivity relationships in the multi parameter setting between metal, support and support modification.
Project-related publications by participating researchers
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Project- and subject-related list of publications |
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F. Flecken, T. Grell, S. Hanf, Transition Metal Complexes of the PPO/POP Ligand: Variable Coordination Chemistry and Photo-Luminescence Properties. Dalton Trans. 2022, 51, 8975–8985. DOI: 10.1039/D2DT01091G. |
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F. Flecken, A. Knapp, T. Grell, C. Dreßler, S. Hanf, Acute Bite Angle POP- and PSP-Type Ligands and Their Trinuclear Copper(I) Complexes: Synthesis and Photo-Luminescence Properties. Inorg. Chem. 2023, 62 (32), 13038–13049. |
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S. Hanf, R. García-Rodríguez, A. D. Bond, E. Hey-Hawkins, D. S. Wright, Sterically-Constrained Tripodal Phosphorus-Bridged Tris-Pyridyl Ligands. Dalton Trans. 2016, 45, 276–283. DOI: 10.1039/C5DT04155D. |
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S. Hanf, T. Grell, J. E. Waters, R. García-Rodríguez, E. Hey-Hawkins, D. S. Wright, Facile Synthesis of a Nickel(0) Phosphine Complex at Ambient Temperature. Chem. Commun. 2020, 56, 7893–7896. DOI: 10.1039/d0cc02142c. |
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S. Hanf, L. A. Rupflin, R. Gläser, S. A. Schunk, Current State of the Art of the Solid Rh-Based Catalyzed Hydroformylation of Short-Chain Olefins. Catalysts 2020, 10 (5), 1–36. DOI: 10.3390/catal10050510. |
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A. Neyyathala, F. Flecken, S. Hanf, A Supported Palladium Phosphide Catalyst for the Wacker-Tsuji-Oxidation of Styrene. ChemPlusChem 2023, 88 (2), e202200431. DOI: 10.1002/CPLU.202200431. |
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A. Neyyathala, F. Flecken, F. Rang, C. Papke, S. Hanf, Support Engineering for the Stabilisation of Heterogeneous Pd3P-Based Catalysts for Heck Coupling Reactions. Chem. Eur. J. 2024, 30, e202302825. DOI: 10.1002/CHEM.202302825. |
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G. Innocenti, S. Emig, L. Meyer, M. Mueller, S. Hanf, S. A. Schunk, A. M. Kindler, C. Sievers, Reaction Mechanism of Tetrahydrofurfuryl Alcohol Hydrogenolysis on Ru/SiO2 Studied by In-Situ FTIR Spectroscopy. ChemCatChem 2022, 14 (22), e202200814. DOI: 10.1002/CCTC.202200814. |
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A. Salazar, B. Wentzel, S. Schimmler, R. Gläser, S. Hanf, S. A. Schunk, How Research Data Management Plans Can Help in Harmonizing Open Science and Approaches in the Digital Economy. Chem. Eur. J. 2023, 29 (9), e202202720. DOI: 10.1002/CHEM.202202720. |
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C. Wulf, M. Beller, T. Boenisch, O. Deutschmann, S. Hanf, N. Kockmann, R. Kraehnert, M. Oezaslan, S. Palkovits, S. Schimmler, S. A. Schunk, K. Wagemann, D. Linke, A Unified Research Data Infrastructure for Catalysis Research – Challenges and Concepts. ChemCatChem 2021, 13 (14), 3223–3236. DOI: 10.1002/CCTC.202001974. |